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Biological Treatment of Hazardous Wastes edited by Prof. Gordon Lewandowski and Dr. Louis DeFilippi, is a comprehensive resource, on how to irreversibly destroy hazardous wastes found in all media (water, air, soils, sludge, dredged materials) by employing engineered microbial reactors and systems.  Biological Treatment describes all of the basics required for understanding and applying biological treatment, and hydrogeological techniques, to real world situations. 

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More than just
biological treatment...

...this book is a comprehensive tool for engineers, applied microbiologists, environmental scientists, biochemists, hydrogeologists and all advanced students in the bioremediation and waste treatment fields.    

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Biological Treatment of Hazardous Wastes
 (click here to purchase)

Gordon A. Lewandowski (Professor, New Jersey Institute of Technology, Newark, NJ) / Louis J. DeFilippi (President, Louis DeFilippi LLC, Palatine, Illinois)
ISBN 0-471-04861-5 Hardcover

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Message from the editor. 

"Biological Treatment of Hazardous Wastes" addresses much more than what the title might indicate.  Even though Wiley lists it under "Earth Science" virtually its entire range encompasses areas outside of that realm.  It is quite heavy on what is considered to be "Engineering".  In addition to an introduction to chapters on  applied and easy to understand aspects of microbiological degradation of aqueous wastes, there are fine chapters on reactor engineering, fixed film reactors, hydrogeologic factors, biofiltration, composting, anaerobic process, case studies, and bioremediation. Unlike most modern scientific books, the index is not simply computer generated but was developed through extensive expert key word search. There are numerous citations throughout the book, making it a first rate reference text.   It should make a fine addition to the library of any environmental professional or a terrific source book for advanced seminars in the environmental field. -Louis DeFilippi, Ph.D.

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Summary

Biological treatment of hazardous wastes utilizes the ability of microorganisms in engineered or natural settings to transform virtually any organic compound, anthropogenic or naturally occurring, into an environmentally benign substance. This book offers balanced coverage of both fundamental principles and practical applications of biological treatment of  hazardous waste, allowing readers to understand the often-complex factors involved in these processes.  

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Expanded Table of Contents and links
Click on chapter number, below, to be taken to expanded table of contents for that chapter, or on blue highlighted links or e-mail (work in progress). 

1.  Suspended-Biomass and Fixed-Film Reactors (Piero M. Armenante).    (more on Prof. Armenante here), (e-mail Prof. Armenante).

2.  Introduction to Microbiological Degradation of Aqueous Waste and Its Application Using a Fixed-Film Reactor (Louis DeFilippi & F. Stephen Lupton).  (e-mail Dr. Louis DeFilippi)

3.  Bioslurry Reactors (Christos Christodoulatos &Agamemnon Koutsospyros.  (more on Prof. Christodoulatos); (more on Prof.   Koutsospyros)

4.  Membrane Biofilm Reactors (Peter Wilderer, Frank R. Kolb & Matthias Kniebusch.).  (more on Prof. Wilderer), (e-mail Prof. Wilderer)

5.  Biofiltration of VOC Vapors (Basil C. Baltzis).  (more on Prof. Baltzis). 

6.  Impact of Biokinetics and Population Dynamics on Engineering Analysis of Biodegradation of Hazardous Wastes (Basil C. Baltzis & Gordon A. Lewandowski).  (more on Prof. Lewandowski), (e-mail Prof. Lewandowski)

7.  Hydrogeologic Factors Affecting Biodegradation Processes (Kelton Barr).  (more on Kelton Barr) (e-mail Dr. Barr)

8.  Assessment of the Potential for Clogging and Its Mitigation During In-Situ Bioremediation (Peter R. Jaffé & Stewart W. Taylor).  (more on Prof. Jaffé)(e-mail Prof. Jaffé)

9.  Design Considerations for In-Situ Remediation of Organic Contaminants (Edward J. Bouwer, Neal D. Durant, Liza P. Wilson & Wei-xian Zhang).   (more on Prof. Bouwer), (e-mail Prof. Bouwer); (more on Dr. Durant here); (more on Prof. Wei-xian Zhang).

10. Pentachlorophenol Biodegradation: Laboratory and Field Studies (Carol D. Litchfield & Madhu Rao).   (more on Prof. Litchfield), 

11. Natural Restoration of PCB-Contaminated Hudson River Sediments (Frank J. Mondello, Daniel Abramowicz & James R. Rhea).  (more on Dr. Mondello here).  

12. Microbes in the Muck: A Look into the Anaerobic World (David Kafkewitz & Monica Togna.  (more on Prof. Kafkewitz)(more on Dr. Togna). 

13. Composting (John A. Hogan).  (More on Dr. Hogan here)

1.  Suspended-Biomass and Fixed-Film Reactors (Piero M. Armenante) 
 

Classification of Reactors for Biological Treatment

    Mechanical Energy Delivery Systems
    Gas Sparging and Off-Gas Collection Requirements
    Continuous and Batch Reactor Operations
    Degree of Homogeneity in Reactors: Well-Mixed vs. Plug Flow Reactors
    Suspended Biomass and Fixed Film Reactors
  Suspended-Biomass Reactors
    Stirred Reactors
    Surface Aerated Reactors
    Reactors Using Diffused Aeration or Gas Dispersion
    Jet Reactors
    Biomass Separators
  Fixed-Film Reactors
    Packed-Bed Reactors
    Trickle-Bed Reactors
    Rotating Disk Reactors
    Fluidized-Bed Reactors
  Notation
  References

 

2.  Introduction to Microbiological Degradation of Aqueous Waste and Its Application Using a Fixed-Film Reactor (Louis DeFilippi & F. Stephen Lupton).
  Use of microorganisms in waste treatment
  Fixed film in the microbial world
  Fixed-film reactor in industrial application
    Comparisons
    Advanced Fixed-Film Reactors
    Description of Mixed Media
    Laboratory-Scale Studies
      Mass Transfer
      Bench-Top Bioreactor
    Field-Scale Bioreactor Studies
      Field Pilot-Scale Reactors
    Industrial Wastewater Treatment and Groundwater Remediation
      Organic Loading Rates
      Economics
      Biological Solids formation
      Pollutant Removal Efficiency
      Process Stability
      Reduced Air Stripping of Volatile Organic Compounds (VOCs)
    Versatility
      Industrial wastewater
      Groundwater
    Dependence of Performance on Microbiology and Process Control
      HRT and SRT
      Effect of Mass Transfer on Microbial Processes
  Summary
    Acknowledgments
  References

 

3.  Bioslurry Reactors (Christos Christodoulatos & Agamemnon Koutsospyros).
  Introduction
  Slurry-Phase Treatment Fundamentals
    Process Description
      Aerated Lagoons
      Low-sheer Airlift Reactors (LSAR)
    Adsorption/Desorption
      The Role of Surfactants in Desorption Enhancement
    Biodegradation
      Kinetics of Contaminant Biodegradation
      The Role of Surfactants in Biodegradation Enhancement
  Factors Affecting Slurry Biodegradation
    System Factors
      pH
      Water/Solids Ratio
      Temperature
      Oxygen
      Aging
      Mixing
      Nutrients
      Microbial Population
      Residence Time
    Contaminant Properties
      Solubility
      Volatility
      Biodegradability
      Toxicity
    Soil Properties
  Design Considerations
  Cost Factors
  References

 

4.  Membrane Biofilm Reactors (Peter Wilderer, Frank R. Kolb & Matthias Kniebusch.).
  Concepts
  Membrane Biofilm Systems
   

Membrane Materials

   

Mass Transfer Across the Membrane

    Biofilm Structure and Stability
  Applications
   

Treatment of PAH Containing Groundwater

    Treatment of Process Wastewater Containing Volatile Organics
  References

 

5.  Biofiltration of VOC Vapors (Basil C. Baltzis).
  Introduction
  Factors Affecting Biofiltration
    Microorganisms and kinetics
    Oxygen availability
    Moisture and temperature
    pH
    Other nutrients
    Packing material
    Other factors
  Process Modeling
   

Mass Balances in the Biofilm

    Mass Balances in the Gas Phase
    Mass Balances in the Solid Phase
  Research Needs and Trends
  Biotrickling Filters
  Conclusions
  References

 

6.  Impact of Biokinetics and Population Dynamics on Engineering Analysis of Biodegradation of Hazardous Wastes (Basil C. Baltzis & Gordon A. Lewandowski).
  Introduction
    Engineering Models
    Biodegradation as a Catalytic Process
    Use Of Mixed Microbial Populations
    Specific Growth Rate
    Problems with Current Methodologies for Kinetic Modeling of Biodegradation
  Single Population - Single Pollutant
    A. Determination of Kinetics
    B. Biodegradation in a Single Continuous Flow Reactor
    C. Biodegradation in a Cascade of Two Vessels
    D. Comparisons Between the One- and Two-Vessel Systems
    E. Use of a Cyclically Operated Reactor
  Competing Populations - Single Pollutant
    A. Kinetic Studies in Batch Reactors
    B. Biodegradation in Continuous Flow Reactors
    C. Biodegradation in a Cyclic Reactor
  Presence of Reaction Intermediates
    A. Use of a Single Culture
    B. Use of Microbial Consortia
  Conclusions
  References

 

7.  Hydrogeologic Factors Affecting Biodegradation Processes (Kelton Barr)
  Flow Parameters
    Porosity
    Permeability
  Transport Parameters
    Solubility
    Sorption
    Mass Transfer
    Dispersion
    Diffusion
    Microbial Transport
  Flow Processes
    Soil Air Flow
    Groundwater Flow
  References

 

8.  Assessment of the Potential for Clogging and Its Mitigation During In-Situ Bioremediation (Peter R. Jaffé & Stewart W. Taylor).
  Clogging During Groundwater Recharge
  Biological Clogging During In Situ Bioremediation: Experimental and Theoretical Results
    Experimental Setup
    Experimental Results
    Discussion of Experimental Results
    Physical Models for Permeability Reduction
  Design considerations/Mitigation
    Design Considerations
    Mitigation of Biofouling During In-Situ Bioremediation
  Summary
  References

 

9.  Design Considerations for In-Situ Remediation of Organic Contaminants (Edward J. Bouwer, Neal D. Durant, Liza P. Wilson & Wei-xian Zhang).
  Microbial Metabolism of Organic Contaminants
  Treatment Approaches
    Intrinsic Bioremediation
      Environmental and Chemical Factors Controlling Subsurface Metabolic Activity
      Groundwater Evidence of Intrinsic Bioremediation
      Microbial Evidence of Intrinsic Bioremediation
    Engineered In-Situ Bioremediation
      Biotransformation Stoichiometry
      Supply of Chemicals
      Introduced Microorganisms for In Situ Bioremediation
  Influence of Mass Transfer on Bioavailability
    Concentration Effects
    Desorption Rate Limitations
    Significance of Sorption During In Situ Bioremediation
    Enhancing Desorption-Limited Biodegradation
  Concluding Remarks
  References

 

10. Pentachlorophenol Biodegradation: Laboratory and Field Studies (Carol D. Litchfield & Madhu Rao).
  Background on the Production and Uses of Pentachlorophenol
  PCP Solubility
  Toxic Effects on Microorganisms
  Microbial Degradation
    Fungal Degradation
    Overview of Aerobic Bacterial Metabolism
      Studies Involving Arthrobacter species
      Studies with Pseudomonas species
      Studies involving Flavobacterium species
      Metabolism by Rhodococcus sp.
    Overview of Anaerobic Degradation of PCP
  Biodegradation Treatability Studies
    Prior Treatment Technologies
    Treatability Studies
      Aerobic Treatment of PCP-Contaminated Wastewaters
      Treatment of PCP Contaminated Waters
      Anaerobic Treatability Studies
      Treatability Studies on PCP Contaminated Soils
    Factors Influencing PCP Degradation in Model Systems
      Acclimated Microbial Populations
      Immobilization of the Microorganisms
      Inhibition of Microbial Activity in Bioreactors
      Effects of Supplemental Carbon Sources on Bioreactor Degradation Rates
      Treatment Train Approaches
  Field Studies
  Emerging Technologies
  Conclusions
  References

 

11. Natural Restoration of PCB-Contaminated Hudson River Sediments (Frank J. Mondello, Daniel Abramowicz & James R. Rhea).
 

Introduction

    PCB Nomenclature and Applications
   

PCB Analysis

   

History of PCBs in the Upper Hudson River

    PCB Biodegradation (Laboratory and Environmental Results)
     

Aerobic PCB Biodegradation

     

Anaerobic PCB Dechlorination

 

PCBs in Sediments

    GE's 1991 Hudson River Sediment Sampling and Analysis Program
   

Spatial Distribution of PCB in upper Hudson River Sediments

    Temporal Trends
   

Impact of Reductive Dechlorination on PCB Distributions

    Benefits of Anaerobic PCB Dechlorination
  References

 

12. Microbes in the Muck: A Look into the Anaerobic World (David Kafkewitz & Monica Togna).
  Why Consider Anaerobes?
  When is Oxygen Absolutely Required?
  Denitrification - A Middle Ground
  Activities of Anaerobes
  Metabolic Strategies of Anaerobes
    Electron Sources and Sinks
    Fermentations
    Hydrogen
  Respirations: Electron Sinks and Sink Organisms
    Methanogens
    Sulfidogens
    Acetogens
    Inorganic Ion Reduction
    Organic Electron Acceptors
  Other Anaerobes
  Significance of Anaerobic Culture Technique
    Anaerobic Media
    The Techniques of Prereduced Media
      Oxygen Exclusion
      Reducing Agents and Indicators
    General method for media preparation
  References
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13. Composting (John A. Hogan).
  Composting Compared to Other Solid-Waste Treatment Processes
  Preparation of Waste for Composting
    Waste Suitability
    Contaminant Availability
    Substrate Density
    Water Content
    Inorganic Nutrients
    pH
    Bioaugmentation
    Bulking Agents
    Initial Mixing
  Process Design and Operation
    Ventilation Configuration
    Oxygen Control
    Temperature Control
    Temperature Setpoint Selection
    Temperature Gradients
    Exhaust Gas Minimization and Treatment
    Water Addition
    Mechanical Agitation
    Extended Treatment (Curing)
  Case Studies
    Laboratory Studies
    Field Studies
  Future Application
    Portable Systems
  Conclusions
  References

There is also an extensive index (a comprehensive and valuable tool for information retrieval: computer generated and then manually expanded and cross-referenced). 

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Independent review of:

Biological Treatment of Hazardous Wastes

Gordon A. Lewandowski and Louis J. DeFilippi, Editors, pp 401.

Publisher:. Wiley – Interscience

We live in safe times. The threats posed by the major killers of human populations such as cholera, pneumonia, tuberculosis and plague have largely disappeared from the developed world and their names no longer strike fear into the populace. Developments in sanitation, nutrition, and medicine have seen life expectancies increase decade after decade. However fear would seem to be a necessary requirement of the human condition, and the real threats of past fears have now been largely replaced by the less tangible threats of industrially generated pollutants. A modern prophesier of doom may well invoke a litany including dioxins, PCB’s, pesticides and perhaps even, oestrogen disrupting substances. However it is true to say that in the 150 years or so since the industrial revolution stimulated the demand for synthetic chemicals, the end products of chemical synthesis have generally been discharged untreated into the environment on the principle of dilute and disperse. And this is just what they have done, such that nowhere on earth can be considered a pristine, pollution-free environment. However the scale of this pollution is now recognised and fortunately its effects are rarely irreversible. The environmental challenge for the synthetic chemist and the chemical engineer is to provide affordable, engineered solutions to restore those environments which are most in need.

It is generally accepted that the most cost-effective and sustainable approach to treating a waste is to employ a microbial option. Our greatest success in waste treatment has been in exploitation of the extremely catholic nutritional abilities of microorganisms, in particular the bacteria and fungi.  Microorganisms are quite remarkable creatures and a testimony to what can be achieved by more than 3 billion years of evolution. Wherever we search on the surface of the planet, there are traces of bacterial colonisation. This includes some of the most hostile environments on earth, such as the polar permafrosts and the deep-sea ocean vents, where the temperature can be in excess of 100oC and the pressures are extreme. It is perhaps unsurprising therefore to find that microorganisms can transform virtually any organic compound, whether man-made or naturally occurring as the editors claim in the preface to this compilation of 13 articles, which attempt to provide both the microbiological and the engineering fundamentals of hazardous waste treatment. It is axiomatic however that microorganisms do not undertake such beneficial transformations without considerable encouragement or there would be no contaminated environments requiring treatment.

There are a large number of different strategies summarised in this book for encouraging microorganisms to degrade specific compounds and there is a good coverage of the options for remediating aquatic environments. Of course many soils are contaminated with organic wastes and their clean up requires a different approach. Both in situ remediation, which considers the subsurface environment as a bioreactor, and ex situ alternatives, which require the design of an engineered reactor, are discussed. Perhaps surprisingly, one approach is through a carefully controlled composting process. I am sure that many gardeners will be delighted to learn that aromatic hydrocarbons, pesticides and PCP can be removed through composting, although it is doubtful if the necessary highly aerobic conditions and temperatures in excess of 450C will be achieved on the average garden plot! The authors have achieved their stated aims of providing a combination of fundamental principles and practical applications, but with 12 of the thirteen chapters written by north American affiliates its contents are inevitably a little parochial. Each chapter is a self contained and scholarly account of one aspect of hazardous waste treatment. Thus within a single volume there are excellent summaries of: the chemical engineering aspects of suspended growth, fixed film and slurry reactors; microbial metabolism in aerobic and anaerobic environments; the influence of hydrogeological factors on microbial activity, and case-studies of decontamination of both aqueous and soil environments. There is much of value in this volume for Environmental Managers of industrial complexes. It illustrates what can be achieved and how it can be achieved; any text which demonstrates the applications of technology to site remediation in such a clear and concise way is to be welcomed.  

Review by: Nigel Horan, Department of Civil Engineering: Research University of Leeds, 18th October 1998

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Also, don't forget to visit our "Books of Interest" page, which has (or will eventually have) many books of interest to the Science and Engineering Community. 

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Some resources of interest on the subject of fixed-film reactors are:

 

Contact Louis DeFilippi, Ph.D. at defilip1@flash.net

or by phone at 1-847-925-8524 (USA)

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Most recent page update:  11/08/08